Archive for August 1st, 2010

A “Manhattan Project” for Zinnias Yields a Key to Cheaper Biofuels

scientists unlock biofuel secrets of zinnia cellsThe common zinnia flower may play a key role in transforming the U.S. from a country under siege from high risk fossil fuels, to a nation powered by cleaner, safer biofuels from renewable sources. Scientists working in collaboration from three national laboratories have used four different kinds of imaging systems to get a molecular-level look into the structure of individual zinnia leaf cells.  The breakthrough will speed further research into more efficient methods for breaking down the woody matter in plants, in order to unlock the sugars that can be processed into biofuels.

The collaboration involved the Lawrence Livermore and Lawrence Berkeley national laboratories along with the National Renewable Energy Laboratory. Combined with new federal investments in solar energy and high tech alternative fuels research, this pull-out-all-stops approach to biofuels is another indication that the Obama administration recognizes the serious threat that continued dependence on fossil fuels poses to the health and security of the U.S.

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Techno-economic Study of Bio-oil to Naptha and Diesel Finds Calculated Costs Competitive with Other Kinds of Alternative Fuels

A team from Iowa State University and ConocoPhillips, Biofuels R&D performed a techno-economic study examining the fast pyrolysis of corn stover to bio-oil with subsequent upgrading of the bio-oil to naphtha and diesel range fuels.

While calculated costs of this biofuel are competitive with other kinds of alternative fuels, they found, further research is required to better determine the effect of feedstock properties and process conditions on the ultimate yield of liquid fuel from bio-oil.

They developed two 2,000 dry tonne per day scenarios: the first scenario separates a fraction of the bio-oil to generate hydrogen on-site for fuel upgrading, while the second scenario relies on merchant hydrogen.

The modeling effort resulted in liquid fuel production rates of 134 and 220 million liters (35 and 58 million gallons US) per year for the hydrogen production and purchase scenarios, respectively. Capital costs for these plants are $287 and $200 million. Fuel product value estimates are $3.09 and $2.11 per gallon of gasoline equivalent ($0.82 and $0.56 per liter).

Pioneer plant analysis estimates capital costs to be $911 and $585 million for construction of a first-of-a-kind fast pyrolysis and upgrading biorefinery with product values of $6.55 and $3.41 per gge ($1.73 and $0.90 per liter).

In 2007, ConocoPhillips established an eight-year, $22.5-million research program at Iowa State University dedicated to developing technologies that produce bio renewable fuels. (Earlier post.)

In 2009, a consortium including TI International, ADM, Albemarle and ConocoPhillips was awarded $3.1-million ARPA-E grant to develop a novel single-step catalytic biomass pyrolysis process with high carbon conversion efficiency to produce stable bio-crude oil with low oxygen content. The technology seeks to combine pyrolysis oil production, stabilization, and upgrading into one process, creating the potential to reduce the demand for imported oil and reducing greenhouse gas emissions by displacing fossil fuels with biofuels. (Earlier post.)

Resources

  • Mark M. Wright, Darren E. Dullard, Justin us A. Sa trio and Robert C. Brown (2010) Techno-economic analysis of biomass fast pyrolysis to transportation fuels. Fuel. doi: 10.1016/JFE


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Genera Energy Breaks Ground on Tennessee’s Biomass Innovation Park

Genera Energy, a for-profit company wholly owned by the University of Tennessee Research Foundation, broke ground on Tennessee’s Biomass Innovation Park, a campus that integrates and optimizes the entire biomass supply chain.

Genera Energy was formed to implement the University of Tennessee’s Biofuels Initiative, a $70.5-million state investment in developing a cellulosic biofuels industry in Tennessee, with a farm field to future fuels approach.

The Biomass Innovation Park will provide harvesting, handling, storage, densification, pre-processing, and transportation for multiple feedstocks including switchgrass. Located adjacent to the Genera/DDCE demonstration-scale biorefinery in Vonore on 21 acres, the campus will serve as the foundation for all biomass feedstock used to create biofuels, biochemicals, bioproducts, biomaterials, biopower and bioenergy.

The facility will initially process up to 50,000 tons of switchgrass, but is designed to handle a range of energy crops and other biomass feedstocks, said Dr. Kelly Tiller, Genera president and CEO.

Genera currently has more than 6,000 acres of switchgrass growing in nine counties located within 50 miles of the Vonore biorefinery. Switchgrass is being grown by farmers under contract with Genera.

The Biomass Innovation Park will also be the site for a $5 million Department of Energy-funded high-tonnage switchgrass bulk handling system and will provide strategic partnership opportunities and serve as a template for regional biomass depots. The first phase of construction is scheduled for completion by the end of 2010, in time to store and process switchgrass following the fall harvest.

The Biomass Innovation Park is designed to accommodate future expansion and introduce new technologies and equipment for processing biomass to meet the specifications of biorefineries and other downstream conversion processes. The Biomass Innovation Park will include two storage silos; an equipment shed; bale storage; office buildings; truck scales for feedstock receiving; pre-engineered biomass processing buildings; and energy crop demonstration plots for switchgrass and other crops grown for bioenergy.


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Texas Awards Terrabon $2.75M to Support Biofuels Work

Texas Governor Rick Perry has awarded $2.75 million from the Texas Emerging Technology Fund (TETF) to Terrabon for its work in biofuel technology development. (Earlier post.)

Governor Perry made the announcement in Laredo, where he and city officials announce the benefits of a water treatment project that will purify 50,000 gallons per day of brackish water for potable use in Laredo’s water supply system using Terrabon technology.

The city’s Santa Isabel Water Treatment Plant will utilize Terrabon’s AdVE technology, developed in partnership with Texas Engineering Experiment Station (TEES), a member of the Texas A&M University System. The AdVE process will remove impurities using advanced vapor compression evaporation to produce drinkable water for Laredo. Further, the project will demonstrate the commercial viability of the desalination technology that also reduces the capital and operating costs of water purification. The pilot plant is being designed in cooperation with American Water’s Applied Management Group, which also will provide operating support.

Terrabon also has successfully produced high-octane gasoline made from non-food biomass at its demonstration facility in Bryan, Texas. Developed again in partnership with TEES, Terrabon’s MixAlco is an advanced bio-refining technology that converts low-cost, readily available, non-food, non-sterile biomass into valuable chemicals such as acetic acid, ketones and alcohols that can be processed into renewable gasoline fuels.

The MixAlco process converts biomass into organic chemicals and alcohols with a multi-stage anaerobic process that includes lime pretreatment, non-sterile acidogenic digestion, product concentration, thermal conversion to ketones and their subsequent hydrogenation to create mixed alcohol end products. Two different versions of the MixAlco process are available. Version one is the original process which produces mixed alcohol fuels. Version two produces carboxylate acids and primary alcohols (ethanol). Terrabon’s pathway to renewable gasoline is via the hydrogenation of a ketone (acetone) to isopropanol, and then the subsequent hydrogenation of isopropanol to gasoline.

The biomass used as feedstock includes municipal solid waste (MSW), sewage sludge, forest product residues such as wood chips, wood molasses and other wood waste, and non-edible energy crops such as sweet sorghum. The process is very robust and requires no sterility, which significantly lowers capital costs.

Terrabon holds the exclusive worldwide license from the Texas A&M System for this technology. After it has built the first few commercial plants, the company intends to license and joint venture this technology with industrial partners and others who play a major role in biomass collection or in transportation. Waste Management and Valero Energy Corporation are also key investors in Terrabon’s efforts to help deploy the company’s technologies on a commercial scale.

Terrabon plans to use the TETF investment to: conduct testing to optimize certain processes included in its biofuel technology; expand its joint research arrangement with the Texas A&M System; and extend the build-out of its demonstration facility in Bryan in order to facilitate processing of MSW and other feed stocks into “green” gasoline and other biofuels.


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BATT Program Awards More Than $8 Million for Innovative Research Projects on Lithium Battery Anodes

The Batteries for Advanced Transportation Technologies (BATT) Program is awarding more than $8 million to eight R&D projects on lithium battery anodes. BATT is funded by the Department of Energy’s Office of Vehicle Technologies and is managed by the Lawrence Berkeley National Laboratory as part of its Carbon Cycle 2.0 initiative.

The FY 2010 BATT Request for Proposals on the “Synthesis and Characterization of Novel Anode Materials and Structures for Use in Lithium Batteries” has resulted in new projects that can help accelerate the application of such batteries in plug-in hybrid electric vehicles and electric vehicles. These projects focus on developing next-generation anodes to increase the energy and decrease the cost of lithium batteries while maintaining safety and cycle life.

The awardees include two national laboratories, five universities, and one private non-profit research institute. The total requested funds are $8.54 million over four years. The selected projects are:

BATT Li-ion Anode Project Awards
Grantee Project Description
Argonne National Laboratory

(Michael Thackeray, Jack Vaughey, Lynn Trahey)

Three-Dimensional Anode Architectures and Materials This project will design high surface-area metal foam architectures as substrates for metal or intermetallic anodes. These new architectures will be superior to conventional laminated electrodes due to the enhanced stability derived from direct chemical bonding of the active materials to the current collector. The goal is to design anodes that will deliver a reversible capacity of at least 500 mAh/g with a lifetime of at least 500 cycles.
Binghamton University

(Stanley Whittingham)

Metal-Based High-Capacity Li-Ion Anodes This project will synthesize nano-sized metal-based anodes, with most emphasis being placed on nano-tin. Additionally, other electroactive species will be incorporated so that greater lithium insertion rates can be obtained for safe and faster charging. The goal is to develop anodes with volumetric energy densities that approach double those of current carbon anodes, while still maintaining at least 400 mAh/g.
Drexel University

(Yury Gogotsi, Michel Barsoum)

New Layered Nanolaminates for Use in Lithium Battery Anodes This project will explore a new class of materials combining the laminate structure of graphite with silicon, tin and other elements that can provide a higher lithium uptake per atom and lead to an improved capacity. The goal is to offer combined advantages of graphite and silicon anodes with a higher capacity than graphite and less expansion, longer cycle life, and a lower cost than silicon nanoparticles.
National Renewable Energy Laboratory and the University of Colorado

(Anne Dillon, Steven George, Se-Hee Lee)

Atomic Layer Deposition for Stabilization of Amorphous Silicon Anodes This project will use atomic layer deposition to coat amorphous-silicon anodes with an artificial solid electrolyte interphase layer to help minimize degradation upon volume expansion of the silicon during charging. In addition, flexible organic coatings will be deposited via molecular layer deposition to accommodate this volume change. The goal is to produce an anode with unprecedented high capacity and high rate that is capable of thousands of cycles.
Pennsylvania State University

(Donghai Wang, Michael Hickner)

Synthesis and Characterization of Polymer-Coated Layered SiOx-Graphene Nanocomposite Anodes This project will synthesize anodes targeted to reach specific capacity of more than 1,500 mAh/g with minimal capacity fading in 500 cycles at 1C rates. The layered structure of graphene sheets and SiOx nanoparticles can accommodate volume change or phase transformation of the SiOx materials by providing good electric contact between highly conductive graphene layers during charge/discharge processes, leading to enhanced cycling stability. An elastic binder polymer with Li-ion conductivity will be used to further accommodate volume change.
Southwest Research Institute

(Kwai S. Chan, Michael Miller, Wuwei Liang)

Synthesis and Characterization of Silicon Clathrates for Anode Applications in Lithium-Ion Batteries This project aims to synthesize silicon clathrate anodes that are designed to exhibit a volume expansion of only 9%, compared with 300% for the lithiation of crystalline silicon. Because of the small volume changes during lithiation, silicon clathrate anodes have the potential for high specific energy density, while avoiding capacity fading and improving battery life.
Stanford University
(Yi Cui)
Wiring Up Silicon Nanoparticles for High-Performance Lithium-Ion Battery Anodes This project will explore a hierarchical porous electrode concept to wire up silicon nanoparticles, which can be synthesized at low cost and in large scale. In addition, this project will investigate strategies to limit electrolyte penetration into the silicon nanoparticle anode and will modify the nanoparticle surface to obtain a stable solid electrolyte interphase layer for long-term cycling.
University of Pittsburgh

(Prashant Kumta)

Nanoscale Heterostructures and Thermoplastic Resin Binders: Novel Li-Ion Anode Systems This project will use cost-effective methods to synthesize amorphous silicon and Li-Si alloys and carbon- and boron-based heterostructures. In addition, this project will explore thermoplastic resin binders with chemical, physical, and electrochemical attributes superior to the currently used poly-vinylidene fluoride for keeping silicon particles in contact and preventing electrode cracking during cycling. The project goals include reversible capacities exceeding 2000 mAh/g and high rate capability.

The BATT program received 88 white papers and encouraged 28 applicants to submit full proposals. A selection committee composed of leading lithium battery experts reviewed each proposal and recommended eight for funding.

BATT is the premier fundamental research program in the US for developing high-performance, rechargeable batteries for electric and hybrid-electric vehicles.


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Biodiesel production shoots up 16% in European Union, output reaches 9M tons

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From 2008 to 2009, biodiesel production in the European Union (EU) jumped 16.6 percent, bringing total output up to nine million tons, according to data released by the European Biodiesel Board (EBB). The increased production further cements the EU’s position as the worldwide leader in biodiesel production. Though a 16.6 percent increase in biodiesel production is substantial, it is dwarfed by the swelling increases witnessed in year’s past. The EU’s year-over-over increases in biodiesel production eclipsed the 50 percent mark in both 2005 and 2006.

While biodiesel production increased in the EU as a whole, several individual countries, including Germany, Greece and the UK, reported a decrease. With gains reported in Austria, Belgium, Finland, Italy, Netherlands, Poland and Spain, the EU’s biodiesel production now represents 65 percent of worldwide output. Click here (PDF) to read the entire report about the production of biofuels in the EU.

[Source: European Biodiesel Board via Green Car Congress | Image: Sashafatcat - C.C. License 2.0]

Biodiesel production shoots up 16% in European Union, output reaches 9M tons originally appeared on Autoblog Green on Sun, 01 Aug 2010 08:26:00 EST. Please see our terms for use of feeds.

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Battle Over Natural Gas Royalties Heats Up in Israel
“The gas belongs to the public” – one of Civil Action Forum’s publicity cartoons.

When massive natural gas reserves were discovered off the coast of Israel in early 2009, it seemed as if the country’s energy problems were solved. Many expected that a resource bonanza was on th…
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Battle Over Natural Gas Royalties Heats Up in Israel
“The gas belongs to the public” – one of Civil Action Forum’s publicity cartoons.

When massive natural gas reserves were discovered off the coast of Israel in early 2009, it seemed as if the country’s energy problems were solved. Many expected that a resource bonanza was on th…
Visit the original post at: TreeHugger

Ugly Fight in Moscow Over Fate of Khimki Forest
russia logging protest khimki forest photo
Yevgenia Chirikova (L) and other environmentalists try to present Russian Prime Minister Vladimir Putin with timber. Photo by Igor Tabakov / Moscow Times

The fate of an urban forest has sparked turmoil between protesters and police in Moscow, where environmentalists say a road-construction proj…
Visit the original post at: TreeHugger

Ugly Fight in Moscow Over Fate of Khimki Forest
russia logging protest khimki forest photo
Yevgenia Chirikova (L) and other environmentalists try to present Russian Prime Minister Vladimir Putin with timber. Photo by Igor Tabakov / Moscow Times

The fate of an urban forest has sparked turmoil between protesters and police in Moscow, where environmentalists say a road-construction proj…
Visit the original post at: TreeHugger

Fresh and Easy’s Farm to Store in 24 Program
avocado dressing 017.JPG
photo: Sara Novak

This is an idea that I hope gets some traction and expands to other grocers across the nation. Fresh & Easy’s Neighborhood Market found such success with their Farm to Store in 24 Program, that they will be expanding it. Customers are ensured through the program, the their produce was picked only 24 hours prior to their purchase, Along with the program, the grocer only sells in-state produce so that they can get it to you in a timely manner. … Read the full story on TreeHugger
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Volcom Drives Jean Donation Program for the Homeless, Donate Yours Today!
volcom jeans recycling photo
Image via Volcom.

Last year, Volcom, in collaboration with the National Coalition for the Homeless, donated over 5,000 pairs of jeans to fifty homeless shelters nation-wide in a jean recycling program called, “Give Jeans a Chance.” This year, the athletic apparel brand is back with 200 more participating Volcom stores in North America and hopes of collecting 10,000+ pairs of jeans. The campaig… Read the full story on TreeHugger
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Weekly Intelligence Brief 27 July – 2 August

Companies, organisations and projects in this round-up include: US Department of Energy, Kahuku Wind Power, Kahuku Wind Power project, First Wind, Clipper Windpower, Xtreme Power, Hawaiian Electric Company, Hawaii Public Utilities Commission, Department of Energy and Climate Change (DECC), Ofgem, Scottish Enterprise and Highlands & Islands Enterprise, The Digest of UK Energy Statistics (DUKES), The Crown Estate, Rhode Island Coastal Resources Management Council (CRMC), Mineral Management Service (MMS), Calder Engineering, Sheringham Shoal offshore wind farm project, Neptune Wind, Department of Interior’s Bureau of Ocean Energy Management, Regulation and Enforcement, University of Maine, and State of Maine Ocean Energy Task Force 

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Solyndra Gets Biggest Chunk of SCE’s 250 MW Distributed Solar Project


Solyndra was the very first of the renewable energy companies funded through the (newly renewable energy-friendly) Department of Energy under Secretary Chu, who guaranteed a $535 million loan so Solyndra could build a factory to make its innovative cylindrical CIGS thin film solar modules. That factory is now due online this fall in the Bay Area’s Fremont, ahead of the original schedule.

Now Southern California Edison (SCE) has awarded Solyndra (through its subsidiary, Photon Solar) a bundle of 20-year power purchase agreements to build about 16 MW of rooftop PV systems distributed atop 15 commercial or industrial buildings in Southern California.

Solyndra’s subsidiary, Photon Solar will build the Solyndra systems, the largest being a 3 MW array on a commercial or industrial building in Buena Park. Seven of its 15 sites will be a megawatt or more. The start-up just completed their largest array to date, a 704 KW system on the LCS Industries building in New Jersey.

The company expects to triple its manufacturing output once the first 250MW of capacity ramps up. It has almost a billion in VC funding for its innovative easy-install tubular CIGS thin film modules.

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